In this work the authors evaluated changes of the structure of aqueous solutions of chlorides of sodium and potassium in various concentrations in the parietal layer by means of the dielectrometry and resonance method. In experiments at 20 ° C, the concentration of sodium and potassium chloride concentration of 0.01 M to 1 M in thenear-wall layer "glass - water solutions" height of less than 1000 microns observed multiple reduction of capacitance of solutions, and Q of an oscillatory circuit and a multiple increase coefficient KS which allows to evaluate the structure of the solutions. It is shown that the structure of the solutions in the wall layer depends on the solution concentration, the nature of the solute and the material of surface. Methods of dielectrometry and resonance are informative in the interpretation of the processes in the fluid layer at the interface, "solid – aqueous solution".
water structure, boundary water, water clusters, electric capacity, resonance
1. Kidalov V.N., Khadartsev A.A. Teziografiya krovi i biologicheskikh zhidkostey / Pod red. A.A. Khadartseva. Tula: Tul´skiy poligrafist, 2009. 244 s.
2. Kidalov V.N., Khadartsev A.A., Bagautdinov Sh.M., Chechetkin A.V. Postoyanstvo nepostoyannogo v teziogrammakh preparatov krovi (k standartizatsii issledovaniy kristallizatsii biologicheskikh zhidkostey). Vestnik novykh meditsinskikh tekhnologiy. 2008. № 4. S. 7–13.
3. Otsenka struktury vody i vodnykh rastvorov khlorida natriya s ispol´zovaniem dielektromet-rii i rezonansnogo metoda / Laptev B.I., Sidorenko G.N., Gorlenko N.P. [i dr.]. Vestnik TGASU. 2013. № 2. S. 235–244.
4. Protsessy strukturoobrazovaniya v vode i v vodnykh rastvorakh / Laptev B.I., Sidorenko G.N., Gorlenko N.P. [i dr.]. Voda i ekologiya. Problemy i resheniya. 2012. N 2/3. S. 26–34.
5. Laptev B.I., Sidorenko G.N., Gorlenko N.P., Sarkisov Yu.S., Antoshkin L.V., Kul´chenko A.K. Elektricheskie svoystva vody pri vneshnikh vozdeystviyakh. Vodoochistka, vodopodgotovka, vodosnabzhe-nie. 2014. № 9. S. 20–27.
6. Levitskiy E. F., Laptev B. I., Sidorenko G.N. Ispol´zovanie metoda dielektrometrii dlya otsenki struktury pit´evykh i mineral´nykh vod. Fizioterapevt. 2013. № 5. S. 3–8.
7. Levitskiy E.F., Laptev B.I. Sidorenko G.N. Elektromagnitnye polya v kurortologii i fizio-terapii. Tomsk, 2000. 127 s.
8. Novye podkhody v biomeditsinskoy tekhnologii na osnove vody pogranichnogo sloya / Post-nov S.E, Mezentseva M.V, Podchernyaeva R.Ya. [i dr.]. Biomeditsinskaya radioelektronika. 2009. T.1. S. 3–15.
9. Neobychnye svoystva vody pogranichnogo sloya / Postnov S.E., Podchernyaeva R.Ya., Mezentse-va M.V. [i dr.]. Vestnik rossiyskoy akademii estestvennykh nauk. 2009. №3. S. 12–15.
10. Samoylov O.Ya. Struktura vodnykh rastvorov elektrolitov i gidratatsiya ionov. M.: AN SSSR, 1957. 182 s.
11. Semikhina L. P. Nizkochastotnaya diel´kometriya zhidkostey v slabykh vikhrevykh elektricheskikh polyakh. Avtoref.dis.dokt. fiz.-mat.nauk. Tyumen´, 2006. 33 s.
12. Smirnov A.N., Syroeshkin A.V. Supranadmolekulyarnye kompleksy vody. Ros. khim. zh. 2004. T.48, N 2. C. 125–135.
13. Voda kak geterogennaya struktura / Syroeshkin A.V., Smirnov A.N., Goncharuk V.V. [i dr.]. Elektronnyy zhurnal «Issledovano v Rossii». 2006. S. 843–854.
14. Uspenskaya E.V. Izuchenie struktury vody na supramolekulyarnom urovne dlya razrabotki no-vykh metodov standartizatsii i kontrolya kachestva mineral´nykh vod i zhidkikh lekarstvennykh form. Avtoref. dis. kand. khim. nauk. M., 2007. 27 c.
15. Michaelides A., Morgenstern K. Ice nanoclusters at hydrophobic metal surfaces. Nature Materials. 2007. V.6. P. 597–601.
